Product ID:ULTRON D
MSDS Date:10/24/1989
FSC:6810
NIIN:00N010807
MSDS Number: BHYSS

ULRICH CHEMICAL,INC

3111 NORTH POST ROAD
INDIANAPOLIS, IN 46226-6566

Emergency Phone: 800-424-9300-CHEMTREC;317-898-8632

Info Phone: 317-898-8632

Preparer: MICHAEL T SCANLON

Cage: HO608

VIGORO IND INC

NORTH BEND, OH 45052 US

Telephone: 513-941-4100

Cage: 3E442

INSPECT AIR CONDITIONING SYS,SPACE HEATERS FOR

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

(IMPACT SENSITIVE,EXPLODE).CHEM ACTIVE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LIQ.EMPTY CONTR HAS RESIDUE (VAP,LIQ);OBS ALL

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 RAT ORAL 43 G/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION:CARDIAC EFFECTS ARE
REPORTED AT HIGH LEVELS.INHALATION OF HIGH CONCENTRATIONS CAN
PRODUCE ASPHYXIATION.CARDIAC ARRHYTHMIA HAS BEEN OBSERVED IN SOME
MONKEYS AT 25,000-50,000 PPM;MICE AT 100, 000 PPM;DOG AT 50,000 PPM
AND AT 5,000 PPM IN PRESENCE OF LARGE DOSES OF EXOGENOUS
EPINEPHRINE (MFR).
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRIT,MAY CAUSE CONJ.SKIN:IRRIT.EXCESS
CONTACT-DEFATTING.INGEST:DISCOMFORT.MAY GIVE SAME SYMPTOMS AS
INHAL.INHAL:LOW LEVELS-DROWSINESS,CONCENTRATION LOSS,"HEAVINESS" IN
HEAD.HIGH LEVELS-CARDIAC E FTS.MILD LIVER EFTS,WEIGHT GAIN
PREVENTION.ANESTHETIC.INTERFERE W/ PSYCHOLOGICAL,PSYCHOMOTOR FUNCT
(EXCITEMENT,INCOORD).
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMED FLUSH W/ LARGE AMTS OF WATER FOR AT LEAST 15
MIN,LIFTING LIDS OCCAS.IF SYMP PERSIST,CONSULT MD.SKIN:FLUSH W/
WATER UNTIL ALL CHEM REMOVED.REMOVE,WASH CONTAM CLOTHING.INGEST:IF
CONSCIOUS,IND UCE VOMIT IMMED BY GIVING TWO GLASSES OF WATER &
TOUCH FINGER TO BACK OF THROAT.CALL MD.INHAL:REMOVE PROMPTLY TO
FRESH AIR.IF BREATHING STOPS GIVE ARTF RESP (MOUTH-TO-MOUTH).HAVE
QUALIFIED (SEE SUPP)

Flash Point:NON-FLAMMABLE
Extinguishing Media:MATERIAL IS NON-FLAMMABLE;USE AN EXTINGUISHING
AGENT SUITABLE FOR SURROUNDING FIRES.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA & FULL PROTECTIVE
EQUIP .USE WATER SPRAY TO KEEP CONTR COOL,TO KEEP ANY SPILLAGE AWAY
FROM FIRE & HEAT,TO KEEP VAPORS DOWN.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCLUDE
FLUORIDES,CHLORIDES & PHOSGENE .MAY FORM EXOTHERMIC RXN W/ SOME
METALS.HAZ DECOMP:HALOGENS,HALOGEN ACID,CARBONYL HALIDES.

Spill Release Procedures:EVACUATE UNPROTECTED PERSONNEL.PROT PERS
SHOULD REMOVE FLAMES,SHUT OFF LEAK IF W/OUT RISK.ABSORB W/
COMMERCIAL ABSORB,SHOVEL INTO METAL DRUMS,CLOSE & PROPERLY
STORE.LARGE SPILL:DIKE W/ COMMERCIAL ABSO RB,PUMP INTO DRUMS,DO NOT
LET PUMP OVERHEAT.
Neutralizing Agent:N/K

Handling and Storage Precautions:STORE IN CLEAN,COOL,DRY,WELL-VENTED
AREA OF LOW FIRE RISK.PROTECT CONTR FROM DMG,KEEP CLSD.DO NOT ENTER
STOR AREA UNLESS ADEQ VENTED.SEE LABEL PREC.
Other Precautions:NO SMKNG IN AREA OF USE.DO NOT USE IN GEN VICIN OF
ARC WELDING,OPEN FLAMES,HOT SURF.HEAT/UV RADIA MAY CAUSE FORM OF
HCL/PHOSGENE .AVOID BRTHG VAP,LIQ CONT W/ EYES,SKIN,CLTHG.TANK
CLEANING PERS U SE ONLY FORMAL TANK ENTRY PROC (SUP DA)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:PROTECTIVE,IMPERVIOUS (PVA,NEOPRENE).
Eye Protection:CHEM WORK GOGG ,FACESHLD OPTIONAL.
Other Protective Equipment:PROT,IMPERVIOUS CLTHG (PVA,NEOPRENE).HIGH
DOSE LEVEL WARNING SIGNS REC (PRINCIPAL EXPOS AREAS).SFTY
SHOWER,EMER (ING 3)
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES.REMOVE & WASH
CLOTHING PROMPTLY UPON CONTAMINATION.
Supplemental Safety and Health
VP:5.6 PSIA @ 21.1C,69.8F.CNDTNS (STAB):WELDING,OTHER HEAT
SOURCES.ENTRY RTE:INHAL/SKIN/INGEST .FIRST AID PROC:OPERATOR GIVE
O*2 AS NEC.CALL MD.DO NOT GIVE ADRENALINE (EPINEPHRINE).OTHER
PREC:BA SED ON SFTY PRINCIPLES/AS REQD BY OSHA.FOLLOW LABEL
PREC.TANKS NOT EFTIVELY FLUSHED OF VAP IF SUMP CONTAINS (SEE ING 2)

Boiling Pt:B.P. Text:47.6C,116F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:6.5,AIR=1
Spec Gravity:1.57 (WATER=1)
Evaporation Rate & Reference:1.3 (ETHER=1)
Solubility in Water:0.035 (% BY WEIGHT)
Appearance and Odor:COLORLESS LIQUID WITH FAINT ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AL PWDR,PWDRD TITANIUM (FLASH/SPK ON HEAVY IMPACT).FINELY DIVIDED
BARIUM (EXPLODE BY FRICTION).LITHIUM SHAVINGS (ING 4)
Stability Condition to Avoid:THERMAL-OXIDATIVE DECOMP BEGINS ABOUT
250C,482F.AVOID ACTIVE METALS,LIGHTED CIGARETTES,OPEN FLAMES,HOT
SPOTS,(SEE SUPP)
Hazardous Decomposition Products:CHLORIDES,FLUORIDES AND PHOSGENE
.HALOGENS,HALOGEN ACIDS,CARBONYL HALIDES.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .CONTACT LOCAL ENVIRONMENTAL
PROTECTION AGENCY FOR ADDITIONAL INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.